PROCESS FOR WORKING UP A MIXTURE COMPRISING ALKENE AND OXYGEN

Application IN/PCT/2002/1055/CHE published 2007-04-06, filed 2002-07-09
The present invention relates to a process for working up a mixture (MI), which comprises essentially propene, propane, oxygen and further chemical compounds which have a lower boiling point compared with propene, and which is a mixture obtained by distillation from a mixture (MO) obtained from a reaction of propene with a hydroperoxide in a solvent using a titanium silicalite catalyst to give propylene oxide comprising propylene oxide, solvent, unconverted propene, propane contained in the propene starting material and oxygen and further chemical compounds which have a lower boiling point compared with propene, in which (i) oxygen is removed from the mixture (MI) by combustion of the oxygen to I give a mixture (M2), arid (ii) the propene is separated off from the mixture (M2) by distillation and is recycled to said reaction of propene with a hydroperoxide in a solvent using a titanium silicalite catalyst, wherein the combustion of the oxygen contained in the mixture (MI) is effected catalytically, the catalysts used for said purpose are selected from the group consisting of noble metals and copper chromite and the catalytic combustion is carried out at a temperature of from 280 to 580 °c.

Applicant

1)BASF AKTIENGESELLSCHAFT
:67056 Ludwigshafen Germany

Inventor

1)TELES, Joaquim, Henrique 2)REHFINGER, Alwin 3)BASSLER, Peter 4)RIEBER, Norbert 5)HEFNER, Werner 6)WENZEL, Anne 7)RUDOLF, Peter No of Pages : 22 No of Claims : 6

International Info

Classification: C07D 301/12
Publication Number: WO/2001/051475
Application Date: 2001-01-12

Priority Information

10001401.1 Germany 2000-01-14