A ZEOLITIC MATERIAL TIQ-6, A MICROPOROUS MATERIAL METIQ-6 AND PROCESSES FOR PREPARATION THEREOF

Application IN/PCT/2002/00840 published 2006-03-10, filed 2002-06-24
The invention relates to a microporous material formed by oxygen, silicon, germanium, aluminium, boron, gallium, zirconium and/or titanium known as TIQ-6, to a method for preparing said material and to its applications as catalyst in oxidation reactions. The TIQ-6 preparation method is based on the synthesis of a gel containing titanium and/or zirconium, hydrothermal treatment thereof under controlled conditions and treatment of the resulting laminar material with an organic compound solution, preferably having a long hydrocarbonated chain containing a proton accepting group. This swollen material is subjected to a specific treatment involving agitation, ultrasound or any other method known in prior art with the purpose of obtaining a delaminated solid with a high outer surface. The invention also relates to a material having similar characteristics as that of TIQ-6 but additionally having organic groups anchored on the surface thereof and called METIQ-6, to a method for preparing the latter and to the utilization thereof as catalyst in oxidation reactions. The incorporation of organic species during synthesis of the material called METIQ-6 is carried out by means of a post-synthesis process on the TIQ-6 material. (FIG). nil

Applicant

CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS., AND UNIVERSIDAD POLITECNICA DE VALENCIA.,
SERRANO 117, D-28006, MADRID, SPAIN. AND CAMINO DE VERA, S/N, D-46022, VALENCIA, SPAIN.

Inventor

CORMA CANOS AVELINO FORNES SEGUI VICENTE DIAZ MORALES URBANO DOMINE MARCELO EDUARDO

International Info

Classification: B01J 29/89
Publication Number: WO 01/37629
Application Date: 2000-11-24

Priority Information

P9902655 SPAIN 1999-11-24